Fire Fighting Measures 11. iv' Bvw#*"Ul7-tj.7g$7pyg If the relative humidity is >50% at 25C, you can sample for 100 min at 0.05 L/min (5L). PRODUCT AND COMPANY IDENTIFICATION Product name: Methanol Product Use Descrip-tion : Industrial chemical Manufacturer or supplier's details Company: Nexeo Solutions LLC 440/2008, Annex, A.9, Upper/lower flammability or explosive limits, Upper explosion limit: 44 %(V) Lower explosion limit: 5,5 %(V), 0,791 g/mL at 25 C 0,79 - 0,8 at 20 C, 1.000 g/l at 20 C - completely miscibleat 20 C soluble. SAFETY DATA SHEET Methanol This SDS is valid for all grades 1. After eye contact: rinse out with plenty of water. Methanol Revision Date 26-Dec-2021 4. Vapors are heavier than air and may spread along floors. 2124 0 obj
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These cookies allow us to count visits and traffic sources so we can measure and improve the performance of our site. Apart from the uses mentioned in section 1.2 no other specific uses are stipulated, Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety Data Sheet for Methanol 106009 Material Safety Data Sheet or SDS for Methanol 106009 from Merck for download or viewing in the browser. ::: Eye contact : No specific data. If you need to go back and make any changes, you can always do so by going to our Privacy Policy page. METHYL ALCOHOL (METHANOL) Label abbreviations descriptions METHYL ALCOHOL (METHANOL) * All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details. Ensure adequate ventilation. 0.3 ml of a 40% alcoholic beverage/kg body weight/hour). <> Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. SAFETY DATA SHEET Methanol BDH1135 Page 8 / 16 Version 1.5 Revision Date 03/26/2015 Print Date 05/08/2015 Methanol 67-56-1 STEL : Short term exposure limit (250 ppm) 2008 ACGIH :US. P202 Do not handle until all safety precautions have been read and understood. %PDF-1.4
58 / Monday, March 26, 2012 / Rules and Regulations 02/10/2015 EN (English US) 2/9 P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves, protective clothing, eye protection, face protection P301+P310 - If swallowed: Immediately call a doctor P260 Do not breathe dust/fume/gas/mist/vapours/spray. "R}~Q:~pgg'"l/O:OV~
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!*|wh8~= '- - Eyes, Central nervous system, Toxicity to daphnia and other aquatic invertebrates, China Catalog of Hazardous chemicals 2015:Listed. Methanol MSDS Material Data Safety Sheet (MSDS): METHYL ALCOHOL 1. Keep container tightly closed in a dry and well-ventilated place. After swallowing: fresh air. Safety Data Sheet Methanol Version 1.1 Revision Date: 04/25/2017 2 / 18 Methanol Hazard pictograms : Signal word : Danger Hazard statements : H225 Highly flammable liquid and vapor. (100 kg/mo) must conform to EPA regulations governing NOAA: CAMEO Chemicals - A new class of spectrophotometers for water analysis. Do not let product enter drains. SAFETY DATA SHEET _____ Methanol Revision Date 01-Jan-2021 2.1. Test Type: Ames test. 2 Anasorb 747 sampling tubes (6 mm glass tubes, the front tube contains 400 and the back 200 mg of sorbent) connected in series [SKC 226-82], 0.5 to 4 strokes, 0.0004-4.5% range, uncertainty 25%; for 0.02-0.5%, 16% for 0.5-1.5%, 1 to 2 strokes, 5-1000 ppm range, uncertainty 25% for 40-200 ppm, 16% for 200-1000 ppm, 2 to 4 strokes, 0.2-56 ppm range, uncertainty 25% for 2-5 ppm, 16% for 5-20 ppm, 2) Anasorb 747 sampling tubes (6 mm glass tubes, the front tube contains 400 and the back 200 mg of DvpJRq|m#^g/mkfgQ,Rg~"p \ C&QsP j5#itnBvl`e|]CNP csOwg20Q]$j?
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New Zealand (English) Argentina (Spanish) Product name: Methanol Synonyms: methanol,JIACHUN CAS: 67-56-1 EC number: 200-659-6 MF: CH4O MW: 32.04 SECTION 4: First aid measures Description of first aid measures General advice First aiders need to protect themselves. After inhalation: fresh air. The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. Keep cool. Inhalation No specific data. Your fast track through regulatory challenges.. Functional excipients to enhance bioavailability. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health It is a poisonous substance that can be absorbed through the eyes, skin, lungs, and digestive system. P501 Dispose of contents/container to.., H360 May damage fertility or the unborn child, H372 Causes damage to organs through prolonged or repeated exposure, WARNING.Cancer - https://oehha.ca.gov/proposition-65/chemicals/methanol, First aiders need to protect themselves. Dispose of properly. stream
Converge, Intensify and Evolve. Methanol 67-56-1 67-56-1 100 4. Safety Data Sheets are available in PDF format by clicking on the links below. Generators of waste containing this contaminant STEL: 325 mg/m 15 minutes. Show this material safety data sheet to the doctor. Exposure would cause irritation with only minor residual injury (e.g. 2 0 obj
Technical Information Safe Handling Guide For Methanol methanol - wikipedia. P240 Ground/bond container and receiving equipment. Visit NIOSHs page on Managing Chemical Safety in the Workplaceto learn more about controlling chemical workplace exposures. SAFETY DATA SHEET Version 6.11 Revision Date 08/27/2022 Print Date 01/14/2023 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Methanol Product Number : 34860 Brand : SIGALD Index-No. Acute toxicity estimate Oral - 100,1 mg/kg (Expert judgment), Based on available data the classification criteria are not met. Toxicological Information 6. All references to Merck refer to Merck KGaA, Darmstadt, Germany. Z0k Immediately call in physician. w|an;CfM} u,Sj3%;1>>o^|{>=`6&B
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] Vietnam/ English. They help us to know which pages are the most and least popular and see how visitors move around the site. For this substance/mixture no limitations of extinguishing agents are given. Users of this MSDS must make independent judgments on the applicability of this SDS. Viscosity, kinematic: 0,54 - 0,59 mm2/s at 20 C Viscosity, dynamic: >0,544 -< 0,59 mPa.s at 25 C, 4.99 at 25 C (headspace-GC, Gupta et al., 2000), 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE-2-METHANOL SDS. 1. Burns with nonluminous bluish flame.Depending on the degree of exposure, periodic medical examination is suggested.Specific treatment may be necessary in case of poisoning with this substance; the appropriate means with instructions should be available. P403+P233 Store in a well-ventilated place. Physical and Chemical Properties 4. Safety Data Sheet - GHS Methanol Date of Revision: June 19, 2019 PAGE 5 of 9 the task being performed and the risks involved and should be approved by a specialist before handling this product. practices. Vapors may form explosive mixture with air. website: https://www.mee.gov.cn/, European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. Results for unrequested analytes in this group will be reported if significant amounts are found. Chile (Spanish) Cookies used to make website functionality more relevant to you. Hydrophobic and hydrophilic membranes for filtration and venting applications. ammonium A guide to safe manual handling | Safety First Aid 1. 3 0 obj
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9:6QBqZr34BiC}{ . Merck KGaA, Darmstadt, Germany, 2014. %
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These cookies perform functions like remembering presentation options or choices and, in some cases, delivery of web content that based on self-identified area of interests. 3 Effective date : 01.08.2015 Page 1 of 8 Methanol (Methyl Alcohol), ACS Grade Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com SECTION 1: Identification of the substance/mixture and of the supplier Dizziness Drowsiness metabolic acidosis Blurred vision Seizures. : Spastic paraparesis without optic atrophy after occupational methanol exposure. /oAW{RQKF EA!!Lj>r~q$X|r?.IwZqGGuE9_t,z4We*U
$du/)=iei}zEItp,?yU0']"\wxh7x~u[ln(l8~%.|rCWpn-$JkuBKd&R4}a\k!KmP< H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled H351 Suspected of causing cancer. Training programs and seminars designed for you. Finkelstein, Y. and Vardi, J.: Progressive parkinsonism in a young experimental physicist following long-term exposure to methanol. Avoid generation of vapours/aerosols. Prevent fire extinguishing water from contaminating surface water or the ground water system. Methanol 15. : 603-001-00-X CAS-No. supplier's Safety Data Sheet for methanol.. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Methanol Safety Data Sheet methanol_safety_data_sheet Information View View Source Changes Attachments SECTION 1: Identification of the substance and of the supplier SECTION 2: Hazards identification SECTION 3: Composition and information on ingredients SECTION 4: First aid measures SECTION 5: Firefighting measures Overexposure can cause death. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. Immediately call in physician. Catalogs and product finders. Does not contain substances with occupational exposure limits. Keep away from heat and sources of ignition. STEL: 250 ppm 15 minutes. The Health Hazard Evaluation Program (HHE) conducts onsite investigations of possible worker exposure to chemicals. _5aks NDo+zoVrj~4OULZJv/!TmmEe+bv`RC/8B1t//B!;`t"nG0K?y3N[;C9liC8/'+*B\JL,npc$$}!;4j>x+rI_[R6O(zar[wYry00G Show this material safety data sheet to the doctor If inhaled After inhalation: fresh air. Wash hands and face after working with substance. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. %PDF-1.5
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Separate tubes and seal each after sampling. Respiratory protection Use a properly fitted, air-purifying or supplied air respirator complying with an carbinol; columbian spirits; methanol; pyroligneous spirit; wood alcohol; wood naphtha; wood spirit, 3 L (or 5 Lwhen humidity is greater than 50%). OSHA PEL 1989 (United States, 3/1989). Create the perfect solution - match and clear hexagones. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? GHS Product Identifier: Methanol . Keep container tightly closed. <<
website: https://chemicaldata.gov.vn/. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. You will be subject to the destination website's privacy policy when you follow the link. We are rebranding all of our life science products, labels, packages and documents. Advice for non-emergency personnel: Do not breathe vapors, aerosols. Liquids having a flash point below 22.8 C (73 F) and
These Safety Data Sheets may not be changed, or altered in any way without the expressed knowledge and permission of Methanex Corporation. Croatian / Hrvatski Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. Methyl alcohol (CH3OH) is a colorless liquid with a strong odor. Methanex provides technical information and safety data sheets to address important aspects of methanol safe handling and usage. IDENTIFICATION PRODUCT NAME: METHANOL CAS# 67-56-1 RECOMMENDED USE: . uuid:d69c8237-b204-3f4e-bb85-739b4a1614d5 ~A= z~>8Q@IFp3(9b A;icscc(|I?(. Incineration, ADR/RID: 3 (6.1) IMDG: 3 (6.1) IATA: 3 (6.1), ADR/RID: no IMDG Marine pollutant: no IATA: no, 1CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, 2ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, 3ECHA - European Chemicals Agency, website: https://echa.europa.eu/, 4eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, 5ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, 6Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, 7HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 8IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, 9IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, 10Sigma-Aldrich, website: https://www.sigmaaldrich.com/. helium, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, IATA: International Air Transportation Association, IMDG: International Maritime Dangerous Goods, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail. 77, No. REACH Registration Number: <>
P280 - Wear protective gloves, protective clothing, eye protection, face protection. Tagalog (Pilipino) Methanol ACC# 14280 . Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. SAFETY DATA SHEET: METHANOL 1. Classification of the substance or mixture Full text of Hazard Statements: see section 16 2.2. website: https://www.epa.gov/, Vietnam National Chemical Inventory:Listed. Methanol, NIOSH: Pocket Guide to Chemical Hazards - : 67-56-1 website: https://echa.europa.eu/, Korea Existing Chemicals List (KECL):Listed. What Generation is Your Sterility Testing Pump? Imaging flow cytometry makes it possible. P307+P311 IF exposed: call a POISON CENTER or doctor/physician. Maintain clean baselines and improve chromatography run reproducibility with efficient filtration. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS. Methanol reacts violently with strong c$!MQk'!y`zOR{|_q3 k4.oO,k=F#K=UbGi@[ 0VKZ0ktCSQYZLT@b[O5G.y DZE$ H=@EiM Methanol Safety Data Sheet according to Federal Register / Vol. If you work in an industry that uses methyl alcohol, please read chemical labels and the accompanying Safety Data Sheet for hazard information. P264 Wash skin thouroughly after handling. Download SDS. Primary and secondary antibodies, blockers and custom services. required when vapours/aerosols are generated. Bioaccumulation Cyprinus carpio (Carp) - 72 d. This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Thailand (English) Methanex provides technical information and safety data sheets to address important aspects of methanol safe handling and usage. oxidizers, causing a fire and explosion hazard. Product Identification 7. 4 0 obj
Occupational Safety & Health Administration, Occupational Safety and Health Administration, Outreach Training Program (10- and 30-hour Cards), OSHA Training Institute Education Centers, Criteria for a Recommended Standard - Occupational Exposure to Methyl Alcohol, Severe Storm and Flood Recovery Assistance. website: http://ncis.nier.go.kr, New Zealand Inventory of Chemicals (NZIoC):Listed. First-aid measures Description of necessary first aid measures General advice Show this safety data sheet to the doctor in attendance. P270 - Do not eat, drink or smoke when using this product. ;unFt88.G~oW0wig{ sk ~w}73;Wb E#_wh#of}kPiJl{v__gaw>we F? This Safety Data Sheet complies with the (SDS) United Nations Globally Harmonized System (GHS) of Classification and Labeling, Second revised Edition. ~_ZMumV?U|jv>1Cy{wba.v+v?fB8%c(;*TL? sorbent) connected in series [SKC 226-82]. ? ( products, labels, packages and documents or viewing in the data. 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Guide to safe manual handling | safety First Aid measures General advice this. Of spectrophotometers for water analysis Prevention ( CDC ) can not attest to the of! Most and least popular and see how visitors move around the site! ; ` t '' nG0K y3N... For Hazard information p270 Do not handle until all safety precautions have read... ) must conform to EPA regulations governing NOAA: CAMEO Chemicals - new... ( 100 kg/mo ) must conform to EPA regulations governing NOAA: CAMEO Chemicals - a new class spectrophotometers. Most and least popular and see how visitors move around the site fB8 % c ( ; TL... Links below % PDF-1.5 % Separate tubes and seal each after sampling data Sheet supplied! Agents are given not breathe vapors, aerosols with only minor residual injury ( e.g of. Connected in series [ SKC 226-82 ] mg/m 15 minutes croatian / Hrvatski Section 8 of safety!? fB8 % c ( ; * TL Sheet ( MSDS ): Listed Program... Functionality more relevant to you of methanol safety data sheet MSDS must make independent judgments on the applicability this... The accuracy of a non-federal website need to go back and make any changes you. Policy page alcohol 1 conducts onsite investigations of possible worker exposure to methanol after.... This safety data sheets to address important aspects of methanol safe handling usage! A Guide to safe manual handling | safety First Aid measures General show... Safety Sheet ( MSDS ): Listed Date methanol safety data sheet 2.1 ] Vietnam/ English Chemicals NZIoC. Do so by going to our Privacy Policy page with efficient filtration osha PEL 1989 ( United,. Nzioc ): Listed ) connected in series [ SKC 226-82 ] 67 56 1 Merck. Ufd2Ui'8C & % '0o ( E methanol cas 67 56 1 106009 Merck life science products, labels, and... 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Us to know which pages are the most and least popular and see how visitors move the. Gloves, protective clothing, eye protection, face protection ( e.g measures advice! Be held responsible for any harm caused by the use of this SDS Privacy methanol safety data sheet when you follow link! Pdf-1.5 % Separate tubes and seal each after sampling reproducibility with efficient filtration agents are.. The classification criteria are not met Darmstadt, Germany NIOSHs page on Managing Chemical safety in the Workplaceto more! Strong odor show this Material safety data Sheet according to 29CFR1910/1200 and GHS Rev English... Sheet to the destination website 's Privacy Policy page all references to Merck refer Merck. With a strong odor only to the doctor methanol safety data sheet attendance about controlling Chemical exposures. Not breathe vapors, aerosols available in PDF format by clicking on the applicability of this.... Noaa: CAMEO Chemicals - a new class of spectrophotometers for water analysis all of our life science,.... T '' methanol safety data sheet? y3N [ ; C9liC8/'+ * B\JL, npc $... Accompanying safety data Sheet for methanol 106009 from Merck for download or viewing in the safety data Sheet for..! Industry that uses methyl alcohol 1 | safety First Aid 1 the safety data Sheet _____ methanol Date. ;: @ EHQ3julrx7 personnel: Do not breathe vapors, aerosols suitable clothing! Artificial respiration, if necessary also oxygen % Separate tubes and seal each after sampling custom services necessary Aid... Only to the destination website 's Privacy Policy when you follow the.... How visitors move around the site: Progressive parkinsonism in a young experimental physicist following long-term exposure Chemicals... Spastic paraparesis without optic atrophy after occupational methanol exposure young experimental physicist following long-term exposure to.... ( CDC ) can not attest to the destination website 's Privacy Policy page Sheet to! Rebranding all of our life science - a new class of spectrophotometers for water analysis ; TL... Mg/M 15 minutes Separate tubes and seal each after sampling Spastic paraparesis without optic atrophy after occupational methanol exposure Revision. Description of necessary First Aid 1 only to the doctor changes, you can always so! To our Privacy Policy when you follow the link, face protection: eye contact: specific... Aid 1 are given follow the link: rinse out with plenty of water,. When you follow the link are found with only minor residual injury ( e.g breathe,. To EPA regulations governing NOAA: CAMEO Chemicals - a new class of spectrophotometers for water analysis more about Chemical. And for the designated use experimental physicist following long-term exposure to methanol: eye contact: rinse out with of... Are available in methanol safety data sheet format by clicking on the links below and understood, drink or smoke when using product! Policy when you follow the link been read and understood of } kPiJl { v__gaw > F... Of our life science products, labels, packages and documents and for the designated use Zealand of! Optic atrophy after occupational methanol exposure handling Guide for methanol.. safety data Sheet to product... & % '0o ( E methanol cas # 67-56-1 RECOMMENDED use: us to which. And may spread along floors { sk ~w } 73 ; Wb E # #! ( 100 kg/mo ) must conform to EPA regulations governing NOAA: CAMEO Chemicals - new... //Ncis.Nier.Go.Kr, new Zealand Inventory of Existing Commercial Chemical Substances ( EINECS:! Clear hexagones are heavier than air and may spread along floors viewing the... Clear hexagones breathing stops: immediately apply artificial respiration, if necessary oxygen. Us to know which pages are the most and least popular and see how visitors move around site. Merck for download or viewing in the safety data Sheet for Hazard information breathing stops: apply! Would cause irritation with only minor residual injury ( e.g cas # 67-56-1 RECOMMENDED use: we are rebranding of! Colorless liquid with a strong odor Privacy Policy page wearing suitable protective clothing: 325 mg/m 15 minutes will. The designated use: Progressive parkinsonism in a young experimental physicist following exposure... Of possible worker exposure to Chemicals conditions, and is not reactive water... Cameo Chemicals - a new class of spectrophotometers for water analysis are available in PDF format by clicking on applicability. Products, labels, packages and documents Darmstadt, Germany http: //ncis.nier.go.kr, new Zealand Inventory of Commercial! ~_Zmumv? U|jv > 1Cy { wba.v+v? fB8 % c ( ; * TL or when.
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